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Hydrophobic MFI-Type Zeolites via Alkali-Cation-Induced Defect Healing: Implications for Adsorbent and Catalyst Design

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Here, we demonstrate that sub-stoichiometric amounts of alkali cations (Na+ and K+) critically govern defect formation during the synthesis of Silicalite-1 (MFI), enabling precise control over framework integrity and surface properties after calcination. Combi... ...