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Structures of hexakis(antipyrine)lead(II) complexes: the first example of the stereochemically active and inactive 6s2 lone pair for one lead(II) complex

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Homoleptic lead(II) complexes with the monodentate O-donor ligand antipyrine (anti or 1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one) were synthesized in the form of triflate (trifluoromethanesulfonate) and perchlorate salts, namely, hexakis(1,5-dimethyl-2... ...