Synthesis, crystal structure and green luminescence of a novel manganese(II)-based hybrid: bis[(tert-butoxycarbonyl)methyltriphenylphosphonium] tetrachloridomanganate(II)
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The title novel phosphonium-based manganese(II) hybrid crystal, {(C24H26O2P)2[MnCl4]}n or (TBTP)2[MnCl4], was synthesized via slow evaporation. Single-crystal X-ray diffraction reveals that it crystallizes in the monoclinic space group P21/n, featuring discret... ...
