Metal-Centered Noncovalent Interactions: A Comparative Insight into π-Hole- and σ-Hole-Directed Bonds
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This article investigates the π-hole-driven interactions of BeCl2, MgCl2, and HgCl2, as well as the σ-hole-directed interactions of MoOF4 and OsO4 with substituted pyridines. Among the π-hole complexes, the Be…N beryllium bond exhibits the highest binding ... ...