A Comparative Study of the Influence of Water and Temperature on the Racemization of Five- and Six-Membered l-Alanine-Derived Imides
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Racemization of l-alanine-derived imides is enhanced with high-water content and elevated temperature in dimethylformamide (DMF). Water hydrolyses DMF to give dimethylamine (DMA) and formic acid (FA), resulting in an increase in the basicity of the reaction me... ...
