Redox implications of oxygen binding in hemoglobin and myoglobin: Thermodynamics of the (Fe3+/Fe2+) oxidation-reduction of heme-bound fluoride complexes versus fluoride binding
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In this study, the thermodynamics of the one-electron (Fe2+/Fe3+) oxidation-reduction of the heme-bound fluoride complexes of adult hemoglobin (Hb-F) and horse heart myoglobin (Mb-F) were addressed to interpret the molecular changes these proteins undergo duri... ...