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Coordination-Engineered Zr Centers in Covalent Organic Frameworks: From O-Zr-O to N-Zr-N for Enhanced Ethylene Polymerization

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The synthesis of ultrahigh-molecular-weight polyethylene (UHMWPE) is often hampered by the inherent compromise in traditional catalysts, such as Ziegler-Natta systems, which struggle to balance high activity with precise control over molecular parameters. Cova... ...