Aurophilic interactions in a mixed-valent AuI/III 4-cyanothiazole complex
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Many compounds possessing close AuI...AuI contacts are known, yet their mixed-valent analogs AuI/AuIII are described in literature as rare. Here we report the structural analysis of a newly obtained complex bis(4-cyanothiazole)gold(I) tetrachloridoaurate(III).... ...