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Electrochemical Oxygen-Atom Transfer to Alkenes and Pyridines with a Mn-Porphyrin Catalyst Using Water as the Source of Oxygen

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Oxygen-atom transfer (OAT) reactions, such as epoxidation, often use stoichiometric high-energy oxygen donors that present safety hazards, especially on large scale. Electrochemistry provides a means to replace these reagents with water as the O-atom donor. He... ...