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Hydroxyl-rich nanocavities on perovskite enable nearly barrierless intramolecular hydrogen transfer for nitrate electroreduction to ammonia

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Electrocatalytic nitrate reduction to ammonia (NITRR) provides a sustainable avenue for simultaneous nitrate mitigation and ammonia synthesis, but the sluggish surface hydrogen migration during NITRR remains a major bottleneck. Here, we show a barrierless hydr... ...