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High-pressure and high-temperature polymorphism of Na2CO3 up to 10 GPa

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We report two new high-pressure polymorphs of sodium carbonate, ε and ε-II, stable over ∼2 GPa and 11 GPa, respectively. The ε polymorph exhibits a doubling of the c unit-cell parameter relative to the γ and β phases, crystallizes in space group Cc, and ... ...