Optimization and Mechanistic Studies of the Electrochemical Dimerization of Primary Alkyl-Bromides and Benzylic Chlorides Utilizing a Nickel(II)/Terpyridine Catalytic System
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Electrochemical reductive homo-coupling of alkyl halides provides a sustainable alternative to metal-powder-based protocols. We report a nickel-catalyzed system operating under mild electroreductive conditions that delivers C(sp3)-C(sp3) dimers efficiently usi... ...
