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Di-Silyl Rhodium(III) and Iridium(III) Complexes as Catalysts in Carbene Insertion Reactions into Hydrosilanes

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Catalytic carbene insertion into Si-H bonds has been recognized as an important strategy for the formation of new Si-C bonds. Herein, we report the synthesis and characterization of two new iridium-(III) complexes bearing silyl-quinoline ligands (SiN, 8-(dimet... ...