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Mechanistic insights into evolution of bioluminescence from luciferyl-adenylate chemiluminescence

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Luciferyl-adenylate (LH2AMP) is the key chemiluminescent intermediate in the bioluminescence reaction catalyzed by beetle luciferases. Whereas the luciferase-catalyzed bioluminescence reactions usually proceed with high quantum yields in the green-yellow regio... ...