Synthesis and crystal structure of di-μ-chlorido-bis-[bis(2,6-di-methyl-pyrazine)-copper(I)] and di-μ-bromido-bis[bis(2,6-di-methyl-pyrazine)copper(I)]
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Crystals of [Cu2Cl2(C6H8N2)4] (1) and of [Cu2Br2(C6H8N2)4] (2), C6H8N2 = 2,6-di-methyl-pyrazine, were obtained from the reaction of CuCl or CuBr with 2,6-di-methyl-pyrazine in aceto-nitrile under solvothermal conditions. Both compounds are isotypic. The asymme... ...