Mo4FeGa17.25- x Ge x : Complementary Point Substitutions, Buffering Frameworks, and Merging of the 18‑ n and Octet Bonding Schemes
{{output}}
We present the discovery of Mo4FeGa17.25-x Ge x (x ∼ 2.1(4), based on determination of Ge content), a complex gallide featuring a variety of point substitution phenomena. Its crystal structure is derived from the Ti2Ni type, in which a diamond network of face... ...