Million-Fold Activation of C-H Bonds by Fluorinated Nonheme FeIV=O Complexes via Second Sphere Equatorial Substitution and Catalytic Epoxidation to Boot
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FeIV=O units found in the active sites of nonheme iron oxygenases and related synthetic analogs are intriguing intermediates capable of performing challenging oxygenation reactions. The first crystal structure of such a crucial species in a synthetic complex, ... ...
