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Impacting the balance between CO2 and proton reduction by control over aggregation in a model π-conjugated N-heterocycle - proflavine

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In this study, we investigated the mechanistic factors that govern the selective photocatalytic reduction of CO2 over protons within a simple π-conjugated N-heterocycle, proflavine. Diluted conditions, where aggregates of 65 nm are formed, favored the selecti... ...