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Direct Electrochemistry of Hydrogenase, Formate Dehydrogenase, CO Dehydrogenase, and Nitrogenase: Wiring Strategies and Mechanistic Insights into Metalloenzymes That Produce Solar Fuels

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Direct electrochemistry (DET), whereby a redox enzyme exchanges electrons with an electrode without the intervention of any mediator, has emerged at the turn of the XXIst century as a powerful tool to investigate redox enzymes. In this review we focus on the e... ...