Synthesis, characterization and electronic properties of the icosahedral Zintl cluster [Ag@Pb12]3
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The icosahedral Zintl cluster [Ag@Pb12]3- has been successfully synthesized via the reaction of K4Pb9 with an NHC-silver complex, finally enriching the group 11 triad of icosahedral plumbaspherenes after nearly ten years of pursuit. This unique series allows u... ...