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β‑BaCO3 Facilitates a Topochemical Reaction Route for the High-Temperature Synthesis of Perovskite-Type (Ba,Ca)(Zr,Ti)O3 via Oxycarbonate Intermediates

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Ferroelectric oxides from the perovskite-type (Ba,Ca)-(Zr,Ti)-O3 system are emerging as one of the upcoming lead-free piezoelectrics for future sensing and actuating applications. Improving their functionality requires a precise adjustment of precursor choice,... ...