Synthesis, Characterization, and Evaluation of the Cobalt-Carbon Bond Strength of (PNNP)CoIII-R Complexes
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Square pyramidal cobalt-(III)-alkyl complexes ((PNCH2CH2NP)-CoIII-R (1-R) and (PNCHCHNP)-CoIII-R (2-R), R = CH3, n Bu, or Bn) were synthesized via oxidative addition of alkyl halides to [(PNCH2CH2NP)-CoI]-[Na-(THF)n] (1-Na) or [(PNCHCHNP)-CoI]-[Na-(THF)n] (2-N... ...
