A Revisit of Co(PMe3)4‑Catalyzed Hydrophosphination of Phenylacetylene with HPPh2
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The low-valent cobalt complex Co-(PMe3)4 was previously reported to catalyze the hydrophosphination of phenylacetylene with HPPh2 to yield (E)-PhCHCH-(PPh2) exclusively. This work provides a more in-depth analysis of the catalytic system showing that Co-(PMe... ...