A PtS-like 42.84 topology arising from the self-assembly of square-planar nodes via organotin units: synthesis and crystal structure of the metal-organic framework {[(PhCH2)3Sn]2Ni(CN)4} n
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The self-assembly of K2[Ni(CN)4] with (PhCH2)3SnCl in a 1:2 molar ratio affords the title three-dimensional coordination polymer, poly[hexa-benzyl-tetra-μ-cyanato-nickel(II)ditin(IV)], [NiSn2(C7H7)6(CN)4] n or {[(PhCH2)3Sn]2Ni(CN)4} n . The asymmetric unit is... ...
