Influence of anionic substitutions on the nonlinear optical and luminescent properties of Ca9.75Eu0.5(VO4)7
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New anion-substituted vanadates, Ca9.75±δEu0.5(XO4)0.1(VO4)6.9 (X = As5+, S6+, Sb5+, Ta5+, Mo6+, and Te4+), are synthesized by a high-temperature solid-state method. Crystal structure, nonlinear optical properties, and photoluminescence excitation (PLE) and ... ...