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Photocatalytic [4 + 1] Annulation of Vinyl Aziridines with Alkyl Halides

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Herein, we develop a photocatalytic [4 + 1] annulation of vinyl aziridines with alkyl halides. The reaction appears to experience radical trigger kinetically favored β-scission of the vinyl aziridine C-N bond, generating transient nitrogen-centered radical, f... ...