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Vanadyl complexes supported by O,O- and N,O-chelate ligation: structures and polymerization catalysis

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Reaction of dibromosalicylic aldehyde and 2,6-diisopropylaniline, followed by sodium borohydride, and 2-chloromethylpyridine hydrochloride/triethylamine, and then [VO(OiPr)3] led to [VO(L)(LH)] (where L = 2,6-iPr2C6H3NCH-2-(O)-C6H2Br2-3,5) (1) as the major p... ...