Molybdenum and vanadium homocitrates and their homologs - towards the local environments and protonations of FeMo/V-cofactors in nitrogenases
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Homocitrate is an organic component in the active site of nitrogenases (N2ase), where their cofactors are in the forms of [Δ-MoFe7S9C(R-Hhomocit)(N-his)(S-cys)], [Δ-VFe7S8C(CO3)(R-Hhomocit/homocit)(N-his)(S-cys)], and [Δ-FeFe7S9C(R-Hhomocit /homocit)(N-his)... ...
