Deciphering the mechanistic insights and reactivity trend of high-valent Mn/Fe/Co-oxo species toward C-H bond activation and oxygen atom transfer
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Understanding the structure and reaction pathways of high-valent metal-oxo species in C-H bond activation and oxygen atom transfer reactions is of great importance for improving their reactivity. Herein, we examine the reactivity of heme-based Mn/Fe/Co-oxo por... ...