Pairs of Zirconium Site and Hydroxyl in MOFs Enable Generating Peroxo Species for Efficiently Tandem Oxidative Condensation of Aromatic Amines
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Selective oxidation of aromatic amines to azoxyarenes is important but challenging owing to complex reaction pathways. Here, we report that constructing pairs of Lewis acidic Zr sites and terminal hydroxyl in zirconium trimesate MOF-808 enables activation of H... ...