Single-crystal to single-crystal transformation in a pentagonal bipyramidal Fe(II) complex with a N3S2 chelating ligand: switching on single-ion magnet properties via axial ligand substitution
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A new pentagonal bipyramidal Fe(II) complex [FeII(H2L)(MeOH)2]Cl2·MeOH (1) with a pentadentate N3S2 chelating ligand 2,6-diacetylpyridine bis(4-N-(4-ethylphenyl)thiosemicarbazone) (H2L) was synthesized. It was found that after exposure to air, desolvation of ... ...
