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Ga-on-In Substitution with Zn Vacancies in Zn3In2S6 Induces Electron-Hole Asymmetry and In─O Bond Weakening for Coupled Two-Electron Oxygen Reduction and H2O2 Stabilization

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Artificial photosynthesis of H2O2 offers a sustainable route to decentralized chemical production, yet remains limited by sluggish oxygen reduction kinetics, rapid charge recombination, and undesired decomposition of H2O2 on catalyst active sites. Herein, we r... ...