Enantioselective Pd-Catalyzed Electrochemical Dearomative Allylation of Tropones: Construction of All-C Quaternary Stereocenters
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A Pd-catalyzed electroreductive enantioselective dearomatization of tropones is documented. High levels of chemoselectivity toward the formation of seven-membered ring ketones featuring a stereochemically controlled all-carbon α-stereocenter are successfully ... ...
