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Alternating Edge- and Face-Sharing Octahedra with Partial Super-Exchange Enabling High-Voltage Layered Cathodes

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Traditional O3-type layered oxides with edge-sharing (ES) octahedra suffer from structural instability under high-voltage operation. To address this, we propose a stable edge-sharing coplanar (ESC) O2-type layered structure. In this structure, Li-O octahedra s... ...