Alkoxycarbonylating Reagents from Tetrahydroquinazoline: Enabling Photoredox Catalyst-Free Construction of C(sp2)-C(sp3) and C(sp2)-C(sp2) Bonds
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We designed and synthesized new alkoxycarbonylating reagents from tetrahydroquinazolinone through direct photoexcitation to generate alkoxycarbonyl radicals with varying alkyl chain lengths that can add to alkenes triggering cyclization to form a C(sp2)-C(sp3)... ...
