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Triflic Anhydride-Mediated Cycloacylation of [60]Fullerene with 1-Naphthoic Acids: Synthesis and Derivatization of [60]Fullerene-Fused Dihydrophenalenones

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An efficient triflic anhydride-mediated synthesis of [60]fullerene (C60)-fused dihydrophenalenones from C60 and 1-naphthoic acids has been developed, representing the first one-step construction of C60-fused polyaromatic ketones under metal-free conditions. In... ...