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Unlocking electrophilic N-aryl intermediates from aryl azides, nitroarenes, and aryl amines in cyclization-migration reactions

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An Account of our development of reactions to construct N-heterocycles by triggering cyclization-migration tandem reactions from aryl azides, nitroarenes, and aryl amines is described. The reactivity patterns of metal N-aryl nitrenes, nitrosoarenes, N-aryl nit... ...