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Cooperativity of the Chalcogen Bond Juxtaposed to the Hydrogen Bond in the (H2X)n, X = O, S, Se, Te, n = 3, 4 Clusters

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Clusters of chalcogen hydrides (H2X)n (X = O, S, Se, Te) provide a powerful testbed for probing their bonding motifs, namely, the competing preference between hydrogen and chalcogen bonds, and their cooperativity. The analysis of 37 trimer and 50 tetramer mini... ...