Electronic Structure Rearrangement via Nitroamine-Nitroimine Tautomerism: Obtaining Thermally Stable and Low-Sensitivity Nitrogen-Rich Nitroamine Energetic Materials
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This work established a synthetic strategy combining nitroamine-nitroimine tautomerism and intramolecular hydrogen bonding, yielding compound 3 with a zwitterionic structure. Compound 3 (D = 8722 m s-1; P = 29.9 GPa) exhibited detonation that paralleled that o... ...