Li+ Promoted the Cyanation of Unactivated C-H Bonds Catalyzed by the Manganese Porphyrin Complex through Biomimetic Oxidation
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Heme and nonheme oxygenases have been known to catalyze the oxidation of unactivated C-H bonds. In most cases, hydroxylated products are formed predominantly via the "oxygen rebound" pathway. Alternatively, under certain conditions where the "oxygen rebound... ...