Rhodium-Catalyzed Reductive Carbonylative Cyclization of Aryl Alkynes with Hydrosilanes via C-H Activation to Access Silyl-Substituted Indanones
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A rhodium-catalyzed reductive carbonylative cyclization for the direct synthesis of 3-silyl-1-indanones from readily available aryl alkynes and hydrosilanes is described. This transformation concurrently introduces a silicon moiety and constructs the indanone ... ...