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Photocatalytic Perfluoroalkenylation of Ketones and Its Application in the Synthesis of Fluorinated Heterocycles

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A mild and efficient photocatalytic method for the α-perfluoroalkenylation of ketones via the corresponding enol silanes has been developed. Using a commercial ruthenium photocatalyst and DABCO under visible light irradiation, perfluoroenones were obtained in... ...