Catalytic Asymmetric Kinetic Resolution of 2,2-Disubstituted Styrenyl Aziridines via Ring Opening with Amines
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We report herein the activation of racemic 2,2-disubstituted styrenyl aziridines by Lewis acid catalysis to undergo ring-opening reactions at a tertiary carbocenter via kinetic resolution with amines. A range of chiral diamine products bearing α-tertiary ster... ...
