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Palladium(0)-Catalyzed Nucleophilic Cyclization of Conjugated Enyne-Carbonyls Leading to Cyclic Allenic Alcohols

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Conjugated enynes bearing carbonyl functionality undergo alkoxylative, alkylative, and aminative cyclizations under palladium(0) catalysis to afford cyclic allenic alcohols. The reaction affords two diastereomers due to the presence of both point chirality at ... ...