Zero valent iron and nickel coordination chemistry: metal atoms as direct approach to bis(benzene)chromium bridged N-heterocyclic silylene complexes
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Synthesis and characterization of iron and nickel metal complexes employing the monodentate N-heterocyclic silylene RSiPh (R = PhC(NtBu)2) is reported. The iron complexes were obtained by reacting the 20 valence electron bis(η6-toluene)iron sandwich generated... ...