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Developing two high-nuclearity Ag nanoclusters with temperature-sensitive fluorescence properties

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Two new high-nuclearity silver nanopolyclusters, templated with chromate and molybdate, were synthesized through a simple synthesis process. The structures of the nanoclusters, with the formulas (CrO4)@Ag19(CCPh)7(Ph2PO2)8(H2O)·(BF4)2·CH3OH (YL-1) and (MoO... ...