Iron-Catalyzed Radical-Mediated 1,3-Azidoalkylation of Bicyclo[1.1.0]butanes: Access to 1,1,3,3-Tetrasubstituted Cyclobutanes via Strain Release
{{output}}
An iron-catalyzed proton-coupled electron transfer (PCET)-mediated radical 1,3-azidoalkylation of bicyclo[1.1.0]butanes (BCBs) with diazo compounds and TMSN3 is presented. Iron-catalyzed PCET activates diazo compounds to generate alkyl radicals rather than the... ...
