Bismuth-Catalyzed Photoinduced Ligand-to-Metal Charge Transfer (LMCT) Hydrodecarbonylation of Aldehydes
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Herein, we disclose a visible-light, bismuth-catalyzed strategy for the hydrodecarbonylation of aliphatic aldehydes. Mechanistic studies highlight chlorine radical formation via Ligand-to-Metal Charge Transfer (LMCT) from in situ generated BiIIICl52-. After C(... ...
