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Cobalt-Catalyzed Intramolecular Dearomative Alkylation of Phenols with Alkenes

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A cobalt-catalyzed intramolecular dearomative ipso-spirocyclization of phenols bearing a tethered alkene has been developed. A range of structurally unique spirocyclodienone lactams were achieved in moderate to excellent yields. Synthetic transformations of th... ...