Regioselective 1,2-Hydrogen Atom Transfer of N-Centered Radicals for C(sp3)-C(sp3) Coupling to Generate 1,2-Diamine Derivatives
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Herein, 2-azaallyl anions are reported as super electron donors (SEDs) in the reduction of N-chlorodialkylamines to generate N-centered radicals (NCRs). The NCRs undergo regioselective net 1,2-hydrogen atom transfer (1,2-HAT) to yield C-centered radicals, whic... ...
